Nickel & Cobalt Alloys

2.4606 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

2.4606 Product Description

Overview

2.4606 is a single-phase, austenitic nickel–chromium–molybdenum–tungsten alloy offering outstanding corrosion resistance across an exceptionally wide range of severe environments. This datasheet presents the material within the European (DIN / EN / Werkstoff-Nummer) standard system.

Its high nickel and molybdenum contents provide resistance under reducing conditions, while the high chromium content gives resistance to oxidising media. Molybdenum and tungsten together confer outstanding resistance to localised corrosion such as pitting and crevice attack, and iron is closely controlled to enhance properties. The very low carbon content minimises grain-boundary carbide precipitation, preserving corrosion resistance in the heat-affected zones of welded joints.

Resistance to general, pitting and crevice corrosion increases with combined (Cr + Mo + W) alloy content, and on this measure 2.4606 ranks above most competitive materials, out-performing the Hastelloy C grades in mixed acids. It offers exceptional resistance to sulphuric and hydrochloric acids and to their mixtures, excellent resistance to stress-corrosion cracking, and excellent behaviour in seawater (general, galvanic and localised corrosion, and hydrogen embrittlement). It is used for the most aggressive media in chemical processing, pollution control, pulp and paper, oil and gas, and waste-management applications, with operating capability up to approximately 1000 °C.

1. Physical Properties

Typical values, annealed condition.

Property Value Unit
Density 8.73 g/cm³
Melting range 1338–1380 °C
Elastic modulus 207 GPa
Coefficient of thermal expansion (20–100 °C) 11.97 µm/m·°C
Maximum operating temperature ~1000 °C
Structure Single-phase austenitic (FCC)

2. Chemical Composition (Limiting, wt %)

Composition per DIN 17744 / 17750 (W.Nr. 2.4606, NiCr21Mo16W).

Element Symbol Min % Max % Role in Alloy
Nickel Ni Balance Austenitic FCC matrix; reducing-media resistance
Chromium Cr 19.0 23.0 Oxidising-media resistance
Molybdenum Mo 15.0 17.0 Reducing-acid + pitting/crevice resistance
Tungsten W 3.0 4.4 Localized-corrosion resistance
Iron Fe 5.0 Residual
Carbon C 0.01 Very low (thermal stability)
Titanium Ti 0.02 0.25 Stabiliser
Manganese Mn 0.75 Deoxidiser
Silicon Si 0.08 Very low (thermal stability)
Phosphorus P 0.04 Residual impurity
Sulphur S 0.02 Residual impurity

Nominal: Ni-21Cr-16Mo-3.8W. High Mo + W give outstanding pitting/crevice resistance (PREN ~51); very low C and Si give thermal stability and weldability.

3. Mechanical Properties

Solution-annealed condition, per DIN 17750/17752 (temper F69) for W.Nr. 2.4606.

Property Value Unit
Tensile strength (Rm) ≥690 MPa
0.2% proof strength (Rp0.2) ≥310 MPa
Elongation at fracture (A) ≥45 %

Values per DIN 17750/17752. Confirm against the inspection certificate (EN 10204).

4. Corrosion Resistance

Environment Performance Notes
Sulphuric acid (H₂SO₄) Outstanding Out-performs Hastelloy C grades in mixed acids
Hydrochloric acid (HCl) Outstanding Exceptional resistance in hot acid solutions
Mixed acids (H₂SO₄ + HCl) Outstanding Superior to competitive Ni-Cr-Mo alloys
Pitting and crevice corrosion Outstanding High combined Cr + Mo + W content
Stress-corrosion cracking Outstanding High nickel content
Seawater / marine Excellent General, galvanic, localised corrosion; hydrogen-embrittlement resistance
Weld heat-affected zone Excellent Ultra-low carbon prevents sensitisation
Oxidising media Very Good High chromium content

5. Heat Treatment

The alloy is a single-phase, solid-solution material and is NOT age-hardenable. Heat treatment is for solution annealing only.

Solution Anneal Purpose: Dissolves secondary phases, restores maximum corrosion resistance and ductility, recrystallises cold-worked structure. Followed by rapid cooling (water quench) to retain the single-phase structure and avoid intermetallic/grain-boundary precipitation.

Cold work is used to increase strength where required (e.g. spring temper); a subsequent solution anneal removes the effects of cold work.

6. Weldability and Joining

Excellent weldability; the ultra-low carbon content preserves corrosion resistance in the heat-affected zone. Matched-composition welding products give as-welded resistance to sulphuric/hydrochloric acids and to crevice and pitting corrosion in hot acid-chloride solutions.

Welding Process Applicability Filler / Consumable
GTAW / TIG Excellent DIN EN ISO 18274 S Ni 6686 (NiCr21Mo16W)
GMAW / MIG Excellent DIN EN ISO 18274 S Ni 6686 (NiCr21Mo16W)
SMAW / stick Excellent DIN EN ISO 14172 E Ni 6686

The welding products are also used for dissimilar-metal and overmatched welding (e.g. joining super-duplex and super-austenitic stainless steels). No post-weld heat treatment is normally required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Work hardening High rate (typical of Ni-Cr-Mo-W alloys); rigid setup, sharp tooling, positive rake
Cutting Low speed, sufficient feed/depth to cut below the work-hardened layer
Coolant Ample flood coolant
Preferred condition Solution-annealed

Forming Processes

Process Notes
Cold forming Readily cold-formed; high work-hardening rate; intermediate solution anneal for heavy reductions
Hot forming Followed by rapid cooling to retain single-phase structure
Wire / spring Available from 0.025 mm to 21 mm; spring temper 1200–1600 MPa

8. Applications

Industry Typical Components Key Requirements
Chemical processing Reaction vessels, heat exchangers, piping for mixed acids Mixed-acid + pitting/crevice resistance
Pollution control Flue-gas desulphurisation (FGD), scrubbers, ducting Hot acid-chloride resistance
Pulp and paper Bleaching equipment, digesters Resistance to oxidising chlorine compounds
Oil and gas Downhole tubulars, fasteners, sour-service components SCC resistance; ISO 15156-3 / ISO 15156
Marine engineering Seawater-handling components, fasteners Seawater localised-corrosion + hydrogen-embrittlement resistance
Waste management Incineration and waste-treatment hardware Aggressive mixed-media resistance

9. Available Product Forms and Standards (EN / DIN System)

Product Form EN / DIN Standard Notes
Rod and bar DIN 17752 · VdTÜV 505 Solution-annealed
Plate, sheet and strip DIN 17750 · VdTÜV 505 Solution-annealed, pickled
Seamless tube DIN 17751 · VdTÜV 505 Solution-annealed
Forgings DIN 17754 Solution-annealed
Composition DIN 17744 All product forms
Welding consumables DIN EN ISO 18274 S Ni 6686 Rod, wire, electrode

Qualified for sour-service per ISO 15156-3 (ISO 15156-3).

10. Comparison with Related Alloys (Werkstoff-Nummer System)

W.Nr. Ni % Cr % Mo % Other Best Used For
2.4606 bal 19–23 15–17 W 3–4.4 Mixed acids; FGD; severe pitting/crevice
2.4819 bal 14.5–16.5 15–17 W 3–4.5 Reducing acids; classic Ni-Cr-Mo-W workhorse
2.4602 bal 20–22.5 12.5–14.5 W 2.5–3.5 Oxidising+reducing; pitting/crevice
2.4856 ≥58 20–23 8–10 Nb 3.15–4.15 Sea-water; chemical process; general
2.4858 38–46 19.5–23.5 2.5–3.5 Cu 1.5–3 Sulphuric acid; economy Fe-Ni-Cr-Mo

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