Nickel & Cobalt Alloys

N04404 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

N04404 Product Description

Overview

N04404 is a nickel–copper alloy with a relatively high copper content, developed for specialised electrical and electronic applications. This datasheet presents the material within the American (ASTM / UNS) standard system.

Its composition is carefully adjusted to provide a very low Curie temperature, low magnetic permeability and good brazing characteristics. The permeability (measured at 27 °F with a field strength of 0.5 oersted) does not exceed 1.1, and because this low permeability is not significantly affected by processing and fabrication, the alloy is particularly suitable for electronic parts. Much of its strength is retained at out-gassing temperatures, and its thermal-expansion characteristics are close enough to those of many other alloys to permit the firing of composite metal tubes with negligible distortion.

The low residual levels of iron, manganese and other elements (compared with Monel 400) support the controlled magnetic and brazing behaviour. The alloy resists seawater, common acids and alkalis like other Ni-Cu materials. It is not hardenable by heat treatment and cannot be hot-worked; it is readily cold-worked with standard tooling. Standard product forms include strip, wire, sheet and tube. Typical applications are electronic components, glass-to-metal and composite-tube assemblies, and other parts requiring low permeability with good brazeability.

1. Physical Properties

Values per manufacturer (Special Metals) data, annealed condition.

Property Value Unit
Density 8.84 g/cm³
Melting range 1300–1350 °C
Young's modulus (20 °C) 179 GPa
Thermal conductivity (20 °C) ~21 W/m·K
Coefficient of thermal expansion (20–100 °C) 13.7 µm/m·°C
Magnetic permeability (0.5 oersted) ≤1.1 Low permeability
Curie temperature Very low
Standard product forms Strip, wire, sheet, tube

2. Chemical Composition (Limiting, wt %)

Limiting composition per manufacturer specification (UNS N04404).

Element Symbol Min % Max % Role in Alloy
Nickel (+ Cobalt) Ni+Co 52.0 57.0 Controlled for low Curie temperature + permeability
Copper Cu Balance High copper content (~44%); electrical properties + brazeability
Iron Fe 0.5 Kept low (controls permeability)
Manganese Mn 0.10 Kept low (controls magnetic behaviour)
Carbon C 0.15 Controlled
Silicon Si 0.10 Kept low
Sulphur S 0.024 Residual impurity

Note: alloy 404 has low residual Fe and Mn (vs Monel 400) and a high copper content, adjusted to give very low Curie temperature, low permeability (≤1.1) and good brazing characteristics for electronic use.

3. Mechanical Properties

Typical room-temperature properties, annealed condition.

Property Value Source
Ultimate tensile strength ~450–550 MPa Annealed
0.2% proof strength (yield) ~150–250 MPa Annealed
Elongation at break ~35–40 % Annealed
Condition Strengthened by cold work only Not heat-treatable

The alloy has good ductility and forms readily by conventional methods. Much of its strength is retained at out-gassing temperatures, which is valuable for electronic and vacuum applications. It is not hardenable by heat treatment. Values are typical; confirm against the mill test certificate for each delivery.

4. Corrosion Resistance

Environment Performance Notes
Seawater / marine Good Ni-Cu base (high copper)
Common acids (reducing) Good Like other Ni-Cu alloys
Alkalis / salts Good Broad resistance
Atmospheric / mild media Excellent Stable Ni-Cu surface
Out-gassing / vacuum service Excellent Retains strength; low gas content
Oxidising media (nitric acid) Poor No chromium — avoid

Note: alloy 404 is selected primarily for its electrical/magnetic and brazing properties; its corrosion resistance is good but it is not a primary corrosion-service alloy like Monel 400.

5. Heat Treatment

A single-phase nickel–copper alloy; not hardenable by heat treatment. Heat treatment is for annealing only; strengthening is by cold work.

Anneal Temperature: 760 °C (1400 °F), approximately one hour, followed by appropriate cooling Purpose: softening and restoration of ductility after cold work.

Important: alloy 404 cannot be hot-worked; it is fabricated by cold working with standard tooling (soft die materials give a better finish). The low permeability is stable through processing and fabrication.

6. Weldability and Joining

Suitable for common welding techniques and noted for its good brazing characteristics — a key design feature for electronic assemblies and composite-tube firing.

Welding Process Applicability Notes
GTAW / TIG · resistance Good Common methods applicable
Brazing Excellent Good brazing characteristics (design feature)
Soldering Suitable For electronic assembly

The thermal-expansion match to many other alloys permits firing of composite metal tubes with negligible distortion. Keep joints clean for reliable electronic service.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machining Conventional techniques (as for other iron alloys); work-hardens
Cold working Standard tooling; soft die materials for better finish
Hot working NOT possible — cannot be hot-worked

Forming Processes

Process Notes
Cold forming Excellent ductility; forms readily by conventional methods
Hot forming Not applicable
Annealing 760 °C (1400 °F) ~1 h after cold work

8. Applications

Industry Typical Components Key Requirements
Electronics Electronic parts requiring low permeability Stable low permeability (≤1.1)
Electronics / vacuum Out-gassing / vacuum-tube components Strength retained at out-gassing temperatures
Composite assemblies Composite metal tubes (co-fired) Matched thermal expansion; brazeability
Glass-to-metal seals Sealing and brazed assemblies Good brazing + controlled expansion
Electrical Components needing Ni-Cu + brazeability Corrosion resistance + low Curie temperature

Note: for marine and chemical corrosion service the nickel-rich Monel 400 is the appropriate grade; alloy 404 is chosen for its electronic/magnetic and brazing properties.

9. Available Product Forms and Standards (ASTM / Designation System)

Product Form Standard / Reference
Strip, sheet and plate UNS N04404 · ASTM F96 (electronic)
Wire UNS N04404
Pipe and tube UNS N04404
Brazing / sealing assemblies ASTM F96 (sealing applications)

Specialised electrical/electronic nickel-copper alloy. UNS N04404; ASTM F96. Not hardenable by heat treatment; cannot be hot-worked.

10. Comparison with Related Alloys (UNS System)

UNS Ni % Key Feature Type Best Used For
N04404 52–57 High-Cu, low Fe/Mn Electronic Ni-Cu Low permeability + brazing; electronic parts
N04400 63–70 Ni-rich (~30 Cu) Solid-solution Ni-Cu Seawater, HF, reducing acids
N04401 43–45 Cu-rich (electrical) Electrical Ni-Cu Precision resistors; contacts
N04405 63–70 S free-machining Free-machining Ni-Cu Screw-machine stock
N05500 63–70 Al+Ti age-hard. Age-hardened Ni-Cu High strength; non-magnetic

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