Nickel & Cobalt Alloys

Alloy 401 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

Alloy 401 Product Description

Overview

Alloy 401 is a nickel–copper alloy designed specifically for specialised electrical and electronic applications. This datasheet presents the material within the American (UNS) standard system.

Unlike the nickel-rich Monel 400 (~67% Ni), alloy 401 is copper-rich: it contains 43–45% nickel-plus-cobalt with the balance copper, a composition chosen to give a very low temperature coefficient of resistance combined with a medium-range electrical resistivity. These characteristics, together with good corrosion resistance across a wide variety of environments, make it well suited to wire-wound precision resistors, bi-metal contacts, resistance heaters and circuits.

It is a ductile, single-phase alloy that, like commercially pure nickel, is low in strength in the annealed condition and is strengthened only by cold work (it does not respond to heat treatment). Standard product forms are strip and wire, in which thin sections it is most often used. It is readily autogenously welded by the gas-tungsten-arc process, joined well by resistance welding, and exhibits good brazing characteristics.

1. Physical Properties

Values per manufacturer (Special Metals / Ulbrich) data, annealed condition.

Property Value Unit
Density 8.88 g/cm³
Melting point (approx.) 1280 °C
Young's modulus (20 °C) 179 GPa
Thermal conductivity (21 °C) 21.0 W/m·K
Electrical resistivity (20 °C) medium-range (~0.49) µΩ·m
Temperature coefficient of resistance Very low
Coefficient of thermal expansion (20–95 °C) 13.7 µm/m·°C
Magnetic response Slightly magnetic / near non-magnetic
Standard product forms Strip and wire

2. Chemical Composition (Limiting, wt %)

Limiting composition per manufacturer specification (UNS N04401).

Element Symbol Min % Max % Role in Alloy
Copper Cu Balance Base element (copper-rich, ~53%); electrical properties
Nickel (+ Cobalt) Ni+Co 43.0 45.0 Controlled level for low TCR + corrosion resistance
Manganese Mn 2.25 Deoxidiser
Iron Fe 0.75 Residual
Cobalt Co 0.25 Residual (counted with Ni)
Carbon C 0.10 Controlled
Silicon Si 0.25 Deoxidiser
Sulphur S 0.015 Residual impurity

Note: alloy 401 is copper-rich (the balance is copper, ~53%), distinct from the nickel-rich Monel 400. The controlled 43–45% Ni+Co level is what gives the low temperature coefficient of resistance for electrical use.

3. Mechanical Properties

Typical room-temperature properties.

Property Value Source
Ultimate tensile strength (annealed) ~415–550 MPa Annealed (low strength)
Ultimate tensile strength (cold-worked) up to ~827 MPa (120 ksi) Cold-worked maximum
Elongation (annealed) ~30–40 % Annealed
Condition Strengthened by cold work only Not heat-treatable

Like commercially pure nickel, alloy 401 is low in strength in the annealed condition and can be cold-worked to a maximum of about 120 ksi. It is not hardenable by heat treatment. Values are typical; confirm against the mill test certificate for each delivery.

4. Corrosion Resistance

Environment Performance Notes
General corrosive conditions Very Good Resistant to a wide variety of environments
Seawater / marine Good Ni-Cu base (copper-rich)
Alkalis / salts Good Broad resistance
Reducing acids Good Non-oxidising conditions
Atmospheric / mild media Excellent Stable Ni-Cu surface
Oxidising media (nitric acid) Poor No chromium — avoid

Note: alloy 401 is selected primarily for its electrical properties; its corrosion resistance is good across many environments but it is not a primary corrosion-service alloy like Monel 400.

5. Heat Treatment

A single-phase nickel–copper alloy; not hardenable by heat treatment. Heat treatment is for annealing only; strengthening is by cold work.

Anneal Temperature: typical Ni-Cu annealing range, followed by appropriate cooling Purpose: softening and restoration of ductility after cold work.

The alloy may be hot-worked if required, and is readily cold-worked using standard tooling (soft die materials give a better finish). Strength is developed by cold work, not by aging.

6. Weldability and Joining

Readily joined, particularly in the thin sections in which it is most often used. Gas-tungsten-arc (GTAW) autogenous welding is the common procedure; resistance welding is very satisfactory; and the alloy brazes well.

Welding Process Applicability Notes
GTAW / TIG (autogenous) Excellent Common method for thin strip/wire
Resistance welding Excellent Very satisfactory for this alloy
Brazing / soldering Good Good brazing characteristics

Keep joints clean. As the alloy is usually supplied as fine strip and wire, thin-section joining methods predominate.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machining Conventional techniques used for iron alloys are applicable
Cold working Standard tooling; soft die materials for better finish
Hot working May be hot-worked if needed

Forming Processes

Process Notes
Cold forming Readily cold-worked; strengthens by cold work
Hot forming Possible if required
Product forms Usually strip, foil, ribbon and wire

8. Applications

Industry Typical Components Key Requirements
Electrical / electronic Wire-wound precision resistors Low temperature coefficient of resistance
Electrical / electronic Bi-metal contacts Electrical + corrosion properties
Electrical Resistance heaters and circuits Medium-range resistivity
Electronics Fine strip, foil and wire components Stable electrical behaviour

Note: alloy 401 is a specialised electrical/electronic material; for marine and chemical corrosion service the nickel-rich Monel 400 is the appropriate grade.

9. Available Product Forms and Standards (ASTM / Designation System)

Product Form Standard / Reference
Wire (round, flat, square, profile) Primary form; UNS N04401
Strip, foil and ribbon Primary form
Bar, rod and other forms On request
Welding Autogenous GTAW; resistance welding; brazing

Specialised electrical/electronic nickel-copper alloy. UNS N04401. Standard product forms are strip and wire; other forms on request. Not hardenable by heat treatment.

10. Comparison with Related Alloys (Alloy Designation System)

Alloy Ni % Key Feature Type Best Used For
Alloy 401 43–45 (Ni+Co) Cu-rich (bal Cu) Electrical Ni-Cu Precision resistors; bi-metal contacts
Alloy 400 63–70 Ni-rich (~30 Cu) Solid-solution Ni-Cu Seawater, HF, reducing acids
Alloy R-405 63–70 S free-machining Free-machining Ni-Cu Screw-machine stock
Alloy K-500 63–70 Al+Ti age-hard. Age-hardened Ni-Cu High strength; non-magnetic
Alloy 200 ≥99.0 Pure Ni Commercially pure Caustic/alkali; conductivity

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