Nickel & Cobalt Alloys

Alloy 20 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

Alloy 20 Product Description

Overview

Alloy 20 is an iron–nickel–chromium–molybdenum–copper austenitic alloy (niobium-stabilised) developed for outstanding resistance to sulphuric acid and a wide range of corrosive chemical environments, including both oxidising and reducing conditions. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.

The copper and molybdenum additions give exceptional resistance to sulphuric and phosphoric acids; the high nickel content provides resistance to chloride-ion stress-corrosion cracking; and niobium stabilisation (Nb = 8 × C to 1.0 %) prevents sensitisation and intergranular attack in welded joints. It also offers useful resistance to nitric acid and to pitting and crevice corrosion — better than 304 stainless and comparable to 316L, while solving the chloride stress-corrosion-cracking problems that affect 316L.

The alloy is readily fabricated into mixing tanks, heat exchangers, process piping, pickling equipment, pumps, valves, fasteners and fittings, and is widely used in the production of gasoline, solvents, explosives, inorganic and organic chemicals, pharmaceuticals, and food and synthetic materials. Its aqueous-corrosion applications are essentially the same as those for the more highly alloyed 825-type material, at lower cost. It is included in NACE MR0175 for sour-service oil-field equipment.

1. Physical Properties

Values per Special Metals official datasheet, annealed condition.

Property Value Unit
Density 8.08 g/cm³
Young's modulus 193 GPa
Shear modulus 76 GPa
Specific heat capacity 500 J/kg·K
Electrical resistivity 1.08 µΩ·m
Thermal conductivity 12.3 W/m·K
Coefficient of thermal expansion (25–100 °C) 14.7 µm/m·°C
Maximum service temperature (continuous) ~800 °C

2. Chemical Composition (Limiting, wt %)

Limiting composition per ASTM B462 / B463 (UNS N08020).

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance Base element; austenitic matrix; cost-effective
Nickel Ni 32.0 38.0 Chloride SCC resistance; austenite stabiliser
Chromium Cr 19.0 21.0 Oxidising-acid resistance; passive film
Copper Cu 3.0 4.0 Key addition; sulphuric-acid resistance
Molybdenum Mo 2.0 3.0 Pitting/crevice and reducing-acid resistance
Niobium (+ Tantalum) Nb 8×C 1.0 Stabiliser; prevents weld sensitisation
Carbon C 0.07 Controlled
Manganese Mn 2.0 Deoxidiser
Silicon Si 1.0 Deoxidiser
Phosphorus P 0.045 Residual impurity
Sulphur S 0.035 Residual impurity

3. Mechanical Properties

Typical room-temperature properties, annealed condition.

Property Value Source
Ultimate tensile strength 620 MPa (90 ksi) Special Metals datasheet
0.2% proof strength (yield) 300 MPa (45 ksi) Special Metals datasheet
Elongation at break 40 % Special Metals datasheet
Hardness (annealed) ~B83 HRB Special Metals datasheet

Cold work substantially raises strength: at 50 % cold reduction, UTS reaches ~1017 MPa and yield ~962 MPa (hardness ~C30). The alloy is not age-hardenable; higher strength is achieved by cold work. Values are typical; confirm against the mill test certificate for each delivery.

4. Corrosion Resistance

Environment Performance Notes
Sulphuric acid (H₂SO₄) Outstanding Copper addition gives exceptional resistance across wide concentration range
Phosphoric acid Excellent Suitable for fertiliser and process duty
Nitric acid Very Good Passes boiling 65% nitric acid test (annealed and sensitised)
Chloride stress-corrosion cracking Excellent High Ni content; passes boiling 42% MgCl₂ test
Pitting and crevice corrosion Good Better than 304; comparable to 316L
Intergranular corrosion Excellent Niobium stabilisation prevents sensitisation
Sulphide stress cracking Excellent Included in NACE MR0175 (Rockwell C 32 max)
Reducing media Good Ni + Mo content

5. Heat Treatment

The alloy is niobium-stabilised austenitic and is NOT age-hardenable. Heat treatment is for annealing only; strength is increased by cold work.

Anneal Temperature: 982–1010 °C (1800–1850 °F), time commensurate with section size Cooling: Air cool Purpose: Softening, recrystallisation, and restoration of corrosion resistance.

Hot Forming Temperature: 760–1175 °C (1400–2150 °F)

Stabilise Anneal is used to optimise resistance to intergranular attack for welded service.

6. Weldability and Joining

Readily joined by conventional welding processes. Niobium stabilisation minimises weld-zone sensitisation. Matched or overmatched nickel-alloy filler metals are used.

Welding Process Applicability Filler / Consumable
GTAW / TIG Excellent AWS A5.14 ERNiCrMo-3 (overmatching)
GMAW / MIG Good AWS A5.14 ERNiCrMo-3 (overmatching)
SMAW / stick Good AWS A5.11 ENiCrMo-3

Overmatching Ni-Cr-Mo filler metals are commonly used to offset elemental segregation in the weld and ensure the joint matches base-metal corrosion resistance.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Work hardening Moderate; austenitic behaviour, similar to stainless
Tooling Sharp, rigid setup; carbide or HSS
Coolant Flood coolant recommended
Preferred condition Annealed

Forming Processes

Process Notes
Hot forming 760–1175 °C
Cold forming Readily formed; tensile rises sharply with cold work (UTS up to ~1017 MPa at 50% reduction)
Annealing between operations 982–1010 °C for heavy reductions

8. Applications

Industry Typical Components Key Requirements
Chemical processing Mixing tanks, heat exchangers, process piping, pickling equipment Sulphuric/phosphoric acid resistance
Pharmaceutical Reaction vessels, process equipment Broad-spectrum corrosion resistance; cleanliness
Petrochemical / oil & gas Pumps, valves, fasteners, fittings; sour-service hardware Acid + chloride resistance; NACE MR0175
Food and synthetic materials Processing equipment Corrosion resistance, hygiene
Pickling / plating Tanks and equipment for acid service Sulphuric-acid resistance

9. Available Product Forms and Standards (ASTM / ASME System)

Product Form ASTM Standard ASME Code
Rod, bar and forging stock ASTM B462 / B472 / B473 ASME SB-462 / SB-472 / SB-473
Plate, sheet and strip ASTM A240 / B463 / B906 ASME SA-240 / SB-463
Seamless pipe and tube ASTM B729 / B468 / B464 ASME SB-729 / SB-468 / SB-464
Welded pipe / tube ASTM B474 / B751 / B775 ASME SB-474 / SB-751
Fittings ASTM B366 ASME SB-366
Welding consumables AWS A5.14 ERNiCrMo-3 (overmatching)

Listed in NACE MR0175 for sour-service (Rockwell C 32 max).

10. Comparison with Related Alloys (Alloy Designation System)

Alloy Ni % Cr % Mo % Other Best Used For
Alloy 20 32–38 19–21 2–3 Cu 3–4 Sulphuric acid; chemical process; SCC resistance
Alloy 825 38–46 19.5–23.5 2.5–3.5 Cu 1.5–3 Higher-Ni acid resistance; phosphoric/sulphuric
Alloy 625 ≥58 20–23 8–10 Nb 3.15–4.15 Sea-water; universal corrosion + strength
Alloy C-276 bal 14.5–16.5 15–17 W 3–4.5 Severe reducing acids; far higher Mo

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